可汗学院:有机化学

可汗学院:有机化学

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37.Nucleophilicity vs.Basicity的笔记

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Nucleophilicity:

kinetic concept

  - how good is it at reacting

  - how fast is it as reacting

  - how little extra energy does it need to react

  - matter with solvent

  • good nucleophilicity = good at reacting
  • in protic solvent: I- > OH- > F-
  • in aprotic solvent: OH- > F- > I-

Basicity:

thermodynamic concept

  - how stable are the reactants or the products

  - how badly something would like to react

  - does not matter with solvent

  • OH- > F- > Cl- > Br- > I-

 

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